Greater Side of Triangle Subtends Greater Angle
Theorem
In any triangle, the greater side subtends the greater angle.
Proof
Let $\triangle ABC$ be a triangle such that $AC$ is greater than $AB$.
Let $AD$ be made equal to $AB$.
Let $BD$ be joined.
Then $\angle ADB$ is an exterior angle of the triangle $\triangle BCD$.
Therefore from $\angle ADB$ is greater than $\angle ACB$.
As $AD = AB$, the triangle $\triangle ABD$ is isosceles.
From Isosceles Triangles have Two Equal Angles, $\angle ADB = \angle ABD$.
Therefore $\angle ABD$ is greater than $\angle ACB$.
Therefore, as $\angle ABC = \angle ABD + \angle DBC$, it follows that $\angle ABC$ is greater than $\angle ACB$.
Hence the result.
$\blacksquare$
Historical Note
This is Proposition 18 of Book I of Euclid's The Elements.
This theorem is the converse of Proposition 19: Greater Angle of Triangle Subtended by Greater Side.